摘要
Pillarenes(or pillararenes),as a new and rapidly developing class of covalent macrocycles,have stimulated a tremendous upsurge of interest in supramolecular chemistry because of their unique features and potentials in fabri-cating functional materials.In addition,metallo-supramolecular chemistry has grown steadily over the last few decades.The presence of metal in supramolecular architectures enables the systematic tuning of their properties and endows them with optical,magnetic,and electric etcetera unusual properties.The marriage of these two fields offers new possibilities for the fabrication of novel functional materials and devices.This review article provides an over-view of recent advancements on pillararene-based metallic supramolecular assemblies.The fabrication and func-tionalities of pillararene-decorated metallic macrocycles,metal-organic frameworks(MOFs),and metal nanoparti-cles are comprehensively summarized and discussed.
基金
support of the Key Basic Re-search Project of Shanghai Science and Technology Commission(No.13JC1402200)
Outstanding Doc-toral Dissertation Cultivation Plan of Action(No.PY2014011).
