摘要
Hierarchical CuO-ZnO/SiO_(2)(CZS)nanofibrous membranes are designed and fabricated to remove Congo red and 4-nitro-phenol two common small molecular pollutants in water.The electrospun SiO_(2) fibrous membrane is serves as the substrate for hydrothermal depositing CuO-ZnO nanosheets.The CZS nanofibrous membrane shows good adsorption characteristics for Congo red due to the hierarchical morphology and the adsorption kinetics where isotherm follows the pseudo-second-order model and Langmuir model,respectively.The maximum adsorption capacity for Congo red is 141.8 mg/g.Moreover,the membrane exhibits excellent catalytic reduction activity for 4-nitrophenol under mild conditions and over 96%of the pollut-ants are degraded within 90 s.The CZS nanofibrous membrane has promising prospects in applications in water treatment and environmental protection because of the good flexibility,easy fabrication,excellent adsorption,and catalytic activity.
基金
supported by National Natural Science Foundation of China(Grant number 51903044)
the Fundamental Research Funds for the Central Universities(Grant number 2232020D-03).