摘要
The emissions of SF6 have been restricted owing to 3400 years of atmospheric lifetime and high global warming potential(GWP)as an insulating gas in gas-insulated electrical equipment.In this study,HFO-1336mzz(E)and N_(2)/CO_(2)mixtures are proposed as SF6 substitutes for their short atmospheric lifetime,low GWP and superior insulation performance.The GWP of HFO-1336mzz(E)is only 18 and its atmospheric lifetime is days to weeks.The breakdown voltage of 25%HFO-1336mzz(E)and N_(2)/CO_(2)mixtures is about 85%that of pure SF6 under alternating current.The self-recovery ability of HFO-1336mzz(E)and CO_(2)mixtures is superior to that of HFO-1336mzz(E)and N_(2)mixtures.The decomposition characteristic of HFO-1336mzz(E)shows that a tiny amount of its gas might initiate a carbonisation reaction to form carbon after multiple breakdown tests,which is verified by observations using energy dispersive X-rays spectroscopy and scanning electron microscope.The acute toxicity test of HFO-1336mzz(E)indicates that the gas is non-toxic.The results show that HFO-1336mzz(E)and N_(2)/CO_(2)mixtures are potential substitutes for SF6 in electrical applications.
基金
National Key R&D Program of China,Grant/Award Numbers:2017YFB0902500,2021YFB2401400
Science and Technology Project of State Grid。
