摘要
咪唑及其衍生物作为一类重要的配体分子,可以通过不同的配位模式与众多主体金属离子作用,形成主体-客体配合物。同时,这些配合物在离子识别、荧光材料、药物设计、磁性材料、自组装、气体吸附和催化剂的研发等领域展现出广阔的应用前景。本文着重综述了咪唑基衍生物配体及其配合物的研究进展,对一些此类新型配合物的合成方法与应用做了详细介绍,并展望了未来发展的方向。
As a kind of extremely imperative ligand molecules,complexes containing the imidazolyl and its derivatives,can form host-guest compound with a considerable number of host metallic ions by differ-ent coordination modes.Simultaneously,these compound show extensive application prospect in many fields,such as ion recognition,fluorescent material,drug design,magnetic material,self-assembly,gas adsorption and catalyst exploitation.The present review mainly focused on the research progress of com-plexes containing the imidazolyl and its derivatives during,with details regarding with the synthetic meth-ods and applications of novel compounds,proposing the prospects for future development trend.
作者
邢宇博
袁守怡
张英杰
董鹏
XING Yu-bo;YUAN Shou-yi;ZHANG Ying-jie;DONG Peng
出处
《有色设备》
2023年第1期42-71,共30页
Nonferrous Metallurgical Equipment
基金
国家自然科学基金项目(52204312)
云南省基础研究重点项目(202101AS070020)。
关键词
咪唑衍生物
配位模式
有机金属化学
配合物
Imidazole derivatives
Coordination modes
Organometallic chemistry
Complexes
