摘要
Advances in cluster science have enabled the preparation of atomically precise metal clusters with one to a hundred atoms under controllable expansion conditions.After introducing typical gas-phase cluster preparation and reaction apparatuses,this work summarized recent progress in preparing pure metal clusters of single-atom resolution,including neutral and ionic ones,with typical examples of Al,V,Nb,Fe,Co,Ni,Rh,Pt,Ag,Cu,and Pb.With the development of soft-landing deposition technology,the size-selective pure metal clusters with strict atomic precision and predictive property will benefit nanomanufacturing down to atomic and near-atomic scales.This work serves as a modest motivation to stimulate the interest of scientists focusing on interdisciplinary subjects.
基金
the Ministry of Science and Technology of the People's Republic of China(No.2020YFA0714602)
the National Natural ScienceFoundationof China(Grant No.21722308and 22003072),the Key Research Program of CAS Frontier Sciences(CAS Grant QYZDBSSWSLHO024)
the National Project Development of Advanced Scientific Instruments Based on Deep Ultraviolet Laser Source(Y31M0112C1)
and the CAS Instrument Development Project(Y5294512C1).