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Stable Diarylamine-Substituted Tris(2,4,6-trichlorophenyl)methyl Radicals: One-Step Synthesis, Near-Infrared Emission, and Redox Chemistry

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摘要 A mild one-step radical-to-radical synthetic strategy has been developed to directly produce a new family of diarylamine-substituted tris(2,4,6-trichlorophenyl)methyl(TTM)radicals TTM-DPA,TTM-DBPA,and TTM-DFA.The obtained TTM radical derivatives are extremely stable during chromatography purification and long-term storage in the solid state.
出处 《CCS Chemistry》 CAS 2022年第9期3190-3203,共14页 中国化学会会刊(英文)
基金 supported by the National Key Research and Development Program of China(nos.2018YFA0703200 and 2018YFA0209401) the National Natural Science Foundation of China(nos.61890940,52073063,51903052,and 21733003) the Shanghai Pujiang Project(no.19PJ1400700),the Natural Science Foundation of Shanghai(no.21ZR1409600) the Program for Professor of Special Appointment(Eastern Scholar)at the Shanghai Institutions of Higher Learning.
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