摘要
选择性加氢是有机合成反应中最为经典的反应之一,在天然产物、药物和工业化学品的制造中有着广泛的应用。传统的加氢反应因为其高温高压、危险系数大和使用贵重金属等诸多不利因素,所以人们一直希望能发现更安全温和的加氢反应方法。近年来,由于电化学加氢方法反应条件温和、能量消耗低及反应进程容易控制等优势越来越受到人们的重视,并取得了许多研究成果。本综述依据电化学加氢反应的化学键类型,对近几年来的不饱和碳碳键电化学加氢相关文献报道进行了归纳和综述,有望为电化学加氢研究提供一定指导意义。
Selective hydrogenation is one of the most classical transformations in organic synthesis reaction and plays a very important role in the manufacture of natural products, pharmaceuticals and industrial chemicals. Among them, electrochemical hydrogenation methods have been increasingly used and reported in recent years due to their mild reaction conditions, low energy consumption and easy control of the reaction process, and a large number of research results have been achieved. This review summarizes and synthesizes literature reports on electrochemical hydrogenation of unsaturated carbon-carbon bonds in recent years based on the type of chemical bonds in electrochemical hydrogenation reactions, hoping to provide some guidance for future research.
作者
庄佳文
王敏
周爱华
ZHUANG Jiawen;WANG min;ZHOU Aihua(College of Pharmacy,Jiangsu University,Zhenjiang 212000,China)
出处
《合成化学》
CAS
2022年第11期909-916,共8页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金项目(31700036)。
关键词
电化学
选择性加氢
化学键类型
不饱和碳碳键
有机合成
electrochemistry
selective hydrogenation
chemical bond type
unsaturated carbon-carbon bonds
organic synthesis
