摘要
近年来,去甲咔咯由于显著的顺磁环电流、高单分子电导率、狭窄的HOMO-LUMO能隙、稳定的氧化还原性能以及特有的化学反应性,引起了科研工作者的广泛关注.综述了近些年去甲咔咯的不同合成方法,重点阐述了在插入、取代、氧化还原、延伸π共轭体系四个方面的衍生化反应,同时对去甲咔咯的发展进行了展望.
In recent years,norcorrole has attracted extensive attention of scientific researchers,owing to its distinct paratropic ring current,high single molecule conductivity,narrow HOMO-LUMO gap,stable redox performance and unique chemical reactivity.The different synthetic methods of norcorrole in recent years are reviewed,with emphasis on the derivatization reactions in four aspects:insertion,substitution,redox and extension ofπconjugated system,and the development of norcorrole is prospected.
作者
李莎
孙雅涵
蒙燕葵
李筱芳
张少伟
Li Sha;Sun Yahan;Meng Yankui;Li Xiaofang;Zhang Shaowei(Key Laboratory of Theoretical Organic Chemistry and Functional Molecules,Ministry of Education,School of Chemistry and Chemical Engineering,Hunan University of Science and Technology,Xiangtan,Hunan 411201)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2022年第8期2390-2405,共16页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.22171076)
湖南省科技创新计划(No.2021RC5028)资助项目。
