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Silver vanadate(Ag_(0.33)V_(2)O_(5))nanorods from Ag intercalated vanadium pentoxide for superior cathode of aqueous zinc-ion batteries 被引量:7

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摘要 Silver vanadate(Ag_(0.33)V_(2)O_(5))nanorods were successfully synthesized by the pre-intercalation of Ag+into the interlayer of V_(2)O_(5)through a sol-gel method,which presented a favorable electrochemical performance of high capacity,rate capacity,and cycle stability.Specific ally,Ag_(0.33)V_(2)O_(5)electrode presented a high capacity of about 311 mAh·g^(-1)at the current density of0.1 A·g^(-1).It also delivered long-term cycling stability(144 mAh·g^(-1)after 500 cycles at 2 A·g^(-1)).The reasons for the superior electrochemical performance were the preintercalation Ag^+extended interlayer distance,and the introduction of elemental silver improved conductivity during charge/discharge.Additionally,the Zn^(2+)storage mechanism was revealed by various characteristic measurements.The prepared Ag_(0.33)V_(2)O_(5)nanorods from the sol-gel method were demonstrated as a promising cathode material for aqueous Zn^(2+)batteries.
出处 《Rare Metals》 SCIE EI CAS CSCD 2022年第8期2844-2852,共9页 稀有金属(英文版)
基金 financially supported by the National Natural Science Foundation of China (No.52101243) the Natural Science Foundation of Guangdong Province (No. 2020A1515010886) the Science and Technology Planning Project of Guangzhou (No.202102010373)
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