摘要
利用实验室小型流化床装置,通过改变CO_(2)、H_(2)O浓度得到不同品位菱镁矿的轻烧产物,通过分解率、吸碘值、XRD、BET、SEM对轻烧产物的理化性质进行表征,研究了轻烧气氛中CO_(2)、H_(2)O含量对产物活性的影响。结果表明,在原料分解完全时,产物的活性由微观结构决定;增大CO_(2)浓度,轻烧产物的吸碘值逐渐降低,晶粒尺寸由小逐渐变大,表面结构由多孔变为少孔,说明CO_(2)的存在降低了产物活性;增大H_(2)O浓度,轻烧产物的吸碘值会逐渐降低,比表面积由大变小,表面结构由疏松多孔变得致密光滑,H_(2)O通过促进氧化镁的烧结来抑制产物的活性;相同工况下,高品位的菱镁矿轻烧产物活性高于低品位。
The light-burned products with different grades of magnesite are obtained by changing the concentrations of CO_(2)and H_(2)O in a small fluidized bed.The physicochemical properties of the light-burned products are characterized by decomposition rate,iodine absorption value,XRD,BET and SEM.The effects of CO_(2)and H_(2)O contents in the light-burned atmosphere on the activity of the products are studied.The results show that the activity of the product is determined by the microstructure when the raw material is completely decomposed.With the increase of CO_(2)concentration,the iodine absorption value of light-burned products gradually decrease,the grain size gradually increase,and the surface structure changed from multiporous to less porous,indicating that the presence of CO_(2) reduced the product activity.With the increase of H_(2)O concentration,the iodine absorption value of the light-burned products will gradually decrease,the specific surface area will decrease from large to small,and the surface structure will become dense and smooth from loose and porous.Under the same working conditions,the activity of light burning products of high grade magnesite is higher than that of low grade magnesite.
作者
王刚
夏志豪
李希艳
张虹
韩振南
宋兴飞
许光文
WANG Gang;XIA Zhihao;LI Xiyan;ZHANG Hong;HAN Zhennan;SONG Xingfei;XU Guangwen(Key Laboratory of Resources Chemicals and Materials Ministry of Education,Shenyang University of Chemical Technology,Shenyang 110142,Liaoning,China)
出处
《化工学报》
EI
CSCD
北大核心
2022年第8期3699-3707,共9页
CIESC Journal
基金
国家重点研发计划项目(2020YFC1909301)
辽宁省首批“揭榜挂帅”科技攻关项目(2021JH1/10400025)。
关键词
流化床
菱镁矿
气氛
活性
轻烧
fluidized bed
magnesite
atmosphere
activity
light-burned
