摘要
Catalytic conversion of CO_(2)into chemicals and fuels is a viable method to reduce carbon emissions and achieve carbon neutrality.Through thermal catalysis,electrocatalysis,and photo(electro)catalysis,CO_(2)can be converted into a wide range of valuable products,including CO,formic acid,methanol,methane,ethanol,acetic acid,propanol,light olefi ns,aromatics,and gasoline,as well as fi ne chemicals.In this mini-review,we summarize the recent progress in heterogeneous catalysis for CO_(2)conversion into chemicals and fuels and highlight some representative studies of diff erent conversion routes.The structure-performance correlations of typical catalytic materials used for the CO_(2)conversion reactions have been revealed by combining advanced in situ/operando spectroscopy and microscopy characterizations and density functional theory cal-culations.Catalytic selectivity toward a single CO_(2)reduction product/fraction should be further improved at an industrially relevant CO_(2)conversion rate with considerable stability in the future.
基金
supported by the National Key R&D Program of China(2021YFA1501503)
the National Natural Science Foundation of China(Nos.22002155,22125205,92045302)
the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17020200)
the CAS Youth Innovation Promotion(Y201938)
the Natural Science Foundation of Liaoning Province(2021-MS-022)
the High-Level Talents Innovation Project of Dalian City(2020RQ038).
