摘要
通过高温固相法制备了NaBaPO_(4)∶Er^(3+)荧光材料。采用化学还原法制备银纳米颗粒(银球与银立方),并修饰到NaBaPO_(4)∶Er^(3+)荧光材料中形成复合材料。利用银纳米颗粒表面等离激元特性实现了多激发光窗口激发下NaBaPO_(4)∶Er^(3+)多光子近红外量子剪裁发光增强。实现了在377 nm与485 nm光激发下,银球纳米颗粒表面等离激元增强NaBaPO_(4)∶Er^(3+)四光子与三光子近红外发光;在519 nm光激发下,银立方纳米颗粒表面等离激元增强NaBaPO_(4)∶Er^(3+)三光子近红外发光。
NaBaPO_(4)∶Er^(3+) was synthesized by solid-state reaction.Ag nanoparticles(NPs)(including Ag ball and Ag cube)were synthesized by chemical reduction method.The surface plasmon resonance of Ag NPs was utilized to enhance the multi-photon near infrared(NIR)quantum cutting emission intensity under multi-excitation.The surface plasmon resonance of Ag ball NPs was utilized to enhance the NIR emission intensity of four-photon and three-photon under the excitation of 377 nm and 485 nm,respectively.The surface plasmon resonance of Ag cube NPs was utilized to enhance three-photon NIR emission intensity under the excitation of 377 nm.
作者
洪锦泉
郑标
曾睿灵
修亦心
曾瑞雅
林可鑫
陈大钦
HONG Jin-quan;ZHENG Biao;ZENG Rui-ling;XIU Yi-xin;ZENG Rui-ya;LIN Ke-xin;CHEN Da-qin(College of Physics and Electronic Information Engineering,Minjiang University,Fuzhou 350108,China;College of Materials and Chemical Engineering,Minjiang University,Fuzhou 350108,China;College of Physics and Energy,Fujiang Normal University,Fuzhou 350007,China)
出处
《发光学报》
EI
CAS
CSCD
北大核心
2022年第7期1052-1060,共9页
Chinese Journal of Luminescence
基金
福建省自然科学基金(2021J011029)
福建省教育厅中青年教师教育科研项目(JAT200405)
福建省大学生创新创业训练计划(202110395009)
闽江学院引进人才科研启动经费(MJY21029)资助项目。
