摘要
介绍了脂肪族聚碳酸酯(APCs)的基本特性,综述了APCs合成工艺、改性、应用等方面的研究进展。其中,酯交换法合成APCs属于清洁生产工艺,具有原料易得、工艺简单、成本较低等优势,更适宜大规模工业化生产。针对APCs热学性能较差的问题,进行改性和功能化可以实现它在可生物降解包装材料、生物医学材料、固态电解质等领域的应用。
The basic properties of aliphatic polycarbonates(APCs)were introduced.The synthesis process,modification and application of APCs were reviewed.Among them,the synthesis of APCs by transesterification is a clean production process,which has the advantages of easy availability of raw materials,simple process and low cost,and is more suitable for large-scale industrial production.In view of the poor thermal performance of APCs,modification and functionalization studies can realize their applications in biodegradable packaging materials,biomedical materials,solid electrolytes and other fields.
作者
冉启鼎
李建国
王自庆
王庆印
王公应
Ran Qiding;Li Jianguo;Wang Ziqing;Wang Qingyin;Wang Gongying(Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu Sichuan 610041,China;University of Chinese Academy of Sciences,Beijing 100049,China;Chengdu Organic Chemistry Co.,Ltd.,Chinese Academy of Sciences,Chengdu Sichuan 610041,China;Shihezi University,Shihezi Xinjiang 832003,China)
出处
《石油化工》
CAS
CSCD
北大核心
2022年第6期707-718,共12页
Petrochemical Technology
基金
2019年中国科学院“西部之光”A类人才培养项目
新疆生产建设兵团重点产业创新发展支撑计划(2021DB004)。
关键词
脂肪族聚碳酸酯
可生物降解
催化剂
改性
功能化
aliphatic polycarbonates
biodegradable
catalyst
modification
functionalization