摘要
通过熔融盐法一步合成具有光催化性的水溶性石墨相氮化碳,并将其按一定比例分散至铸膜液基体制得K, Na-PHI/PVDF复合膜.采用XRD、FTIR、SEM、孔隙率、接触角、水通量等测试手段对改性膜的性能进行表征测试.结果表明水溶性氮化碳粒子的引入提高了铸膜液的分相速率,改变了膜的表面形态和化学性质,复合膜的纯水通量由49.76 L/(m^(2)·h)增至224.40L/(m^(2)·h),接触角降为53.90°,通量恢复率为83.73%,总污染率下降,可逆污染比例增加.复合膜对牛血清白蛋白和亚甲基蓝溶液的截留率分别为55.53%和89.88%,且具有一定的光催化性,可见光下270 min内可将10 mg/L亚甲基蓝溶液降解至0.56 mg/L,重复光催化降解率维持在74.50%左右.
In this study, the photocatalytic water-soluble graphite carbon nitride was synthesized by molten salt method in one step, and dispersed in a certain proportion to the casting solution to obtain K,Na-PHI/PVDF composite membrane.The characteristice of the modified membrane were determined using XRD,FTIR,SEM,prosity, water contact angle and water flux measurements.The results showed that the introduction of K, Na-PHI accelerated the phase separation rate of the casting solution and changed the pore structure and pore size of the composite membrane.The pure water flux of composite membrane increased from 49.76 L/(m^(2)·h) to 224.4 L/(m^(2)·h),the contact angle decreased to 53.9°,the flux recovery rate was 83.73%.The total pollution rate decreased, and the proportion of reversibel pollution increased.The separation of BSA and the degradation of MB on composite membrane were 55.53% and 89.88%,respectively, the K,Na-PHI/PVDF membrane has excellent photocatalytic properties. The photocatalytic degradation of 10 mg/L MB could be reduced to 0.56 mg/L in 270 min and the repeat photocatalytic degradation rate was maintained at about 74.50%.
作者
王慧雅
WANG Huiya(School of Environmental Engineering,Nanjing Institute of Technology,Nanjing 211167,China)
出处
《膜科学与技术》
CAS
CSCD
北大核心
2022年第3期41-50,59,共11页
Membrane Science and Technology
基金
江苏省科技厅“含油污泥无害化深度处理关键技术集成装备研发及产业化”(BA2018004)。
关键词
水溶性
氮化碳
PVDF
抗污染性
光催化性
water-soluble
graphitic carbon nitride
PVDF
anti-pollution
photocatalysis
