期刊文献+

载体预处理对炭化树脂负载磷钨酸催化剂烷基化活性的影响

Effect of Pretreatment on the Adsorption of PW_(12)on the Carbonized Resin and its Catalytic Activity
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摘要 烷基化反应中一直沿用的催化剂H2 SO4,HF对环境污染较大 ,腐蚀设备与产物分离困难。文中详细讨论了影响固体酸催化剂PW12 在炭化树脂吸附过程中受预处理的影响。通过实验确定此催化剂制备过程中的适宜预处理条件 ,如预处理溶剂 ,预处理溶剂的浓度。并结合理论进行了分析。 Existing industrial alkylation processes employ corrosive and environmental hazardous HF and H2SO4 as catalysts The catalysts have many disadvantages such as pollution , corrosion and difficulty of separating the product and the catalyst For these safety and environmental reasons their substitution with a noncorrosive solid catalyst is desirable This research focuses on the adsorption of the PW12 on carbonized resin which has high activity and is environmental friendlyThe relationship between the acid pretreatment and the activity of catalyst has been studied experimentally and the best pretreatment condition was obtained A theoretical analysis is made
出处 《长春工业大学学报》 CAS 2002年第B08期83-86,共4页 Journal of Changchun University of Technology
基金 吉林省科技厅科学技术发展基金资助项目(吉科合字第970523 1号)
关键词 负载磷钨酸催化剂 烷基化活性 预处理 固体酸催化剂 催化剂载体 吸附量 炭化树脂 烷基化反应 石油化工 solid acid catalyst carrier alkylation dissolution absorption carbonized resin
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