摘要
Pervaporation(PV)is an emerging separation technique for liquid mixture.Mixed matrix membranes(MMMs)often demonstrate trade-off relationship between separation factor and flux.In this study,by changing the organic linkers(2-methyl imidazolate,imidazole-2-carboxaldehyde,2-ethyl imidazolate),ZIF-8,ZIF-90 and MAF-6 were prepared and filled in polydimethylsiloxane(PDMS)membranes for dealcoholization of 5%(mass)n-butanol solution,and the membranes properties and pervaporation performances were adjusted.Compared with the pure PDMS membrane,the addition of ZIF-8 resulted in a 9%increase in flux(1136 g·m^(-2)·h^(-1))and a 22.5%increase in separation factor(28.3),displaying antitrade-off effect.For the MAF-6/PDMS MMMs(2.0%mass loading),the pervaporation separation index(PSI)and separation factor were 32347 g·m^(-2)·h^(-1) and 58.6 respectively(increased by 34%and 154%in contrast with that of the pure PDMS membrane),and the corresponding permeation flux was 552 g·m^(-2)·h^(-1),presenting great potential in the removal butanol from water.It was deduced that the large aperture size combined with moderate hydrophobicity of metal–organic frameworks(MOFs)favor the concurrent increase in permeability and selectivity.
基金
supported by the National Natural Science Foundation of China (Nos. 22008028, 22102022 and 22166002)
the Opening Project of Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices (PMND202003)
Foshan (Southern China) Institute for New Materials (2021AYF25015)
State Key Laboratory of Nuclear Resources and Environment of East China University of Technology (NRE202116)
the Training Program of National College Students Innovation and Entrepreneurship (202110405009)
