摘要
Van der Waals heterojunctions(vdWHs)provide an excellent material system for the research of heterojunction-enhanced Raman scattering(HERS)due to their complexity and diversity.However,the traditional two-dimensional vdWHs are not conducive to the full utilization of near-field light due to the limitation of single dimension.Herein,we fabricate T-shaped mixed-dimensional SnSe_(2)/ReS_(2) vdWHs via chemical vapor deposition and wetting transfer method,and demonstrate that the mixed-dimensional vdWHs can be used as ultrasensitive HERS chips based on the effective photo-induced charge transfer.Besides,the radiative energy transfer effect enhanced by near-field light further magnifies the HERS signals,improving the detection limit of rhodamine 6G(R6G)to femtomolar level.Furthermore,we demonstrate that the ultrasensitive screening of crystal violet in multicomponent solutions adsorbed on SnSe_(2)/ReS_(2) vdWHs can be achieved by adjusting the laser wavelength,which has not been achieved by noble metal materials.This work provides new insights into the mixed-dimensional vdWHs and demonstrates the great application potential of T-shaped heterojunctions.
基金
supported by the National Natural Science Foundation of China(No.11874108).
