摘要
芳酮类化合物具有多种生物活性,同时也是重要的精细化工品,因此其合成方法受到了广泛关注.对近五至八年来芳酮类化合物的合成方法进行总结,通过对其反应机理进行探讨,将这些反应大致分为三类,即通过过渡金属催化机理的偶联反应、通过自由基机理的反应及通过其他机理的反应,期望为芳酮类化合物的合成新方法提供启发.
Aroyl compounds exhibit various biological activities and are important fine chemicals as well.Therefore,their synthetic methods have attracted considerable attention.It is the first time to summarize the synthetic methods of aroyl compounds in the past five to eight years.These reactions can be classified into three parts by their reaction mechanism,namely,coupling reaction catalyzed transition metals,the free radical mechanism and aromylation reactions carried out by other mechanisms.It is expected that inspiration of new synthetic methods will be provided for the synthesis of compounds bear aroyl group in this review.
作者
刘亮
刘文波
崔冬梅
曾明
Liu Liang;Liu Wenbo;Cui Dong-Mei;Zeng Ming(School of Pharmacy and Life Science,Jiujiang University,Jiujiang,Jiangxi 332005;College of Pharmaceutical Science,Zhejiang University of Technology,Hangzhou 310014)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2021年第11期4289-4305,共17页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.21967013)
江西省自然科学基金青年基金(No.21967013)
江西省教育厅基金(No.GJJ201825)
江西省卫生建康委科技计划(No.202131074)资助项目.
关键词
芳甲酰基
反应机理
合成方法
aroyl group
reaction mechanism
synthetic method
