摘要
采用异丁醛和碱通过微反应仪器合成十二碳醇酯。实验选用异丁醛和NaOH,系统地研究了碱的浓度、含量、温度对微反应的影响。研究表明:当异丁醛和NaOH流速比为1.1︰0.1(流速单位:mL/min),反应温度为50℃,NaOH浓度为30%,目标产物收率达86.5%。
Dodecyl alcohol ester was synthesized through microreaction with iso-butyraldehyde and alkali.Iso-butyraldehyde and NaOH were selected for the experiment and the effects of the alkali concentration,content and temperature on microreaction were systematically studied.The results show that when the iso-butyraldehyde/NaOH flow velocity ratio is 1.1∶0.1(unit:mL/min),the reaction temperature is 50℃ and the concentration of NaOH is 30%,the yield of the target product is 86.5%.
作者
张海飞
操凡
张世元
崔唯
杨林
丁家怡
ZHANG Hai-fei;CAO Fan;ZHANG Shi-yuan;CUI Wei;YANG Lin;DING Jia-yi(Yancheng Institute of Technology,Yancheng 224000,Jiangsu,China;Runtai Chemical Co.,Ltd.,Taizhou 225500,Jiangsu,China)
出处
《中国涂料》
CAS
2021年第5期20-23,共4页
China Coatings
关键词
异丁醛
氢氧化钠
十二碳醇酯
酯化反应
微反应
iso-butyraldehyde
NaOH
dodecyl alcohol ester
esterification reaction
microreaction
