摘要
采用化学气体传感器对有害酸性气体进行实时有效的监测具有重要意义。目前的传统材料在灵敏度、选择性和稳定性等方面仍存在很大问题。金属有机框架材料(MOFs)是一种具有多孔结构的有机-无机杂化材料,具有孔隙率结构丰富、孔结构可调节和比表面积大等特点,已成为当今新功能材料研究的热点。MOFs材料的优良特性为解决上述问题提供了很好的思路和方向,在化学气体传感器的传感层上引入MOFs材料或MOFs衍生的各种纳米材料可以提高其选择性和灵敏度。主要综述了近年来基于MOFs材料的化学气体传感器对酸性气体的传感性能,并对其未来的发展进行了展望。
Chemical gas sensors are significant in effective and real-time monitoring of harmful acidic gas.However,there are still some problems in sensitivity,selectivity and stability of traditional materials.Metal organic frameworks(MOFs)are a kind of organic-inorganic hybrid materials with porous structure,which have become a hotspot in the research of new functional materials due to their rich porosity structure,adjustable pore structure and large specific surface area.The excellent characteristics of MOFs provide a good idea and direction to solve the above problems.The selectivity and sensitivity of chemical gas sensors can be improved by introducing MOFs or various nanomaterials derived from MOFs on the sensing layer.The sensing performances of chemical gas sensors based on MOFs in recent years are reviewed,and its future development is prospected.
作者
郝肖柯
张秀玲
翟振宇
李从举
HAO Xiaoke;ZHANG Xiuling;ZHAI Zhenyu;LI Congju(Key Laboratory of Resource-Oriented Treatment of Industrial Pollutants,Beijing 100083,China;School of Energy and Environmental Engineering,University of Science and Technology Beijing,Beijing 100083,China)
出处
《精细化工》
EI
CAS
CSCD
北大核心
2021年第2期249-258,293,共11页
Fine Chemicals
基金
国家自然科学基金(51973015)
中央高校基本科研业务费专项资金(06500100,06121062)
中国博士后科学基金(2019M660019)
北京市自然科学基金(2202029)
北京市青年人才托举工程。
