摘要
采用水热法制备金属骨架材料UTSA-16,以此为钴源,通过程序升温法制备Co-P@C催化剂并对其在苯酐的加氢脱氧反应中的催化性能进行研究.通过XRD表征分析Co-P@C催化剂的组成和结构.Co-P@C催化剂中有Co2P和CoP相.Co-P@C催化剂在温和的反应条件下(220℃和4.0 MPa)具有良好的加氢脱氧催化活性,对产物苯酞的选择性超过了40%.
UTSA-16 was prepared by hydrothermal method and used for synthesizing cobalt phosphide catalyst.Co-P@C catalyst has been rapidly synthesized via a temperature-programmed reaction and applied for the hydrodeoxygenation of phthalic anhydride.The synthesized Co-P@C catalyst was analyzed and characterized by X-ray diffraction.Co-P@C catalyst included the phases of Co2P and CoP.Co-P@C catalyst exhibited good activity under mild reaction conditions(220℃and 4.0 MPa),in which the selectivity to phthalide is more than 40%.
作者
张亮亮
陈勇强
ZHANG Liang-liang;CHEN Yong-qiang(College of Chemistry and Chemical Engineering,Jinzhong University,Jinzhong,Shanxi,030619,China)
出处
《晋中学院学报》
2020年第3期32-36,共5页
Journal of Jinzhong University
基金
晋中学院“1331工程”“环境催化与植物修复创客团队”(jzxycktd2019032)
山西省“1331工程”“功能MOFs及其衍生材料的制备与性能创新团队”(PY201817).
关键词
程序升温法
磷化钴
加氢脱氧
苯酐
temperature-programmed
cobalt phosphide
hydrodeoxygenation
phthalic anhydride