摘要
综述了碳四烯烃齐聚反应中各类齐聚催化剂的研究进展情况,介绍了不同催化剂上碳四烯烃齐聚反应的机理,并对齐聚催化剂的发展方向进行了展望.开发出性能更加优异的催化剂,特别是通过对催化剂的微观结构和宏观性能的设计和调整,提高催化剂的活性、选择性和稳定性等性能,是今后的主要研究方向,同时,开发资源利用率高、低投资和低生产成本的碳四烯烃齐聚工艺也非常关键.
The advances in catalysts for C4 olefin oligomerization were reviewed.The catalytic mechanisms of different catalysts for C4 olefin oligomerization were introduced.And the research and development direction of oligomerization catalysts was also discussed.It was of great significance to develop catalysts with better performance,especially to improve the activity,stability and lifetime of catalysts by designing and adjusting the microstructure and macroscopic properties of catalysts,and it would be the main research direction in the future.Meanwhile,developing the C4 olefin oligomerization process with higher resource utilization,lower investment and lower production cost were also very critical.
作者
卜婷婷
李修仪
周金波
董炳利
黄剑锋
马艳捷
BU Tingting;LI Xiuyi;ZHOU Jinbo;DONG Bingli;HUANG Jianfeng;MA Yanjie(PetroChina Petrochemical Research Institute,Lanzhou Chemical Research Center,Lanzhou 730060,China)
出处
《化学反应工程与工艺》
CAS
北大核心
2019年第4期375-384,共10页
Chemical Reaction Engineering and Technology
基金
中国石油天然气股份有限公司科技部项目(2018E-03)。
关键词
烯烃齐聚
催化剂
机理
活性
稳定性
olefin oligomerization
catalyst
mechanisms
activity
stability
