摘要
选用具有柔性弯角的4,4’-二苯醚二甲酸(4,4’-oxy-bis(benzoate),缩写为obaH 2)协同N-甲基二乙醇胺(N-methyldiethanolamine,缩写为MedeaH 2)与氯化钴在乙醇溶剂中合成出一个新颖的二维层Co 3簇配合物,即[Co 3(MedeaH)2(oba)2]·2EtOH,通过X-射线单晶衍射测定发现该钴配合物含有特殊方向的一维孔道结构,利用气体吸附实验证明该孔道的存在,并对其进行了红外光谱分析、热重分析、X-射线粉末衍射表征.
Herein,4,4’-oxy-bis(benzoate)(obaH 2)was selected as the flexible and bent ligand to mix with N-methyldiethanolamine(MedeaH 2)and cobalt chloride in ethanol solvent,resulting in a novel Co 3 cluster complex.It was found from X-ray single crystal diffraction that the cobalt complex contained an unique one-dimensional channel.The pore structure was further confirmed by N 2 gas adsorption experiments.The resultant complex has been also characterized by FT-IR spectrum,TG Analysis,X-ray powder diffraction.
作者
孙光辉
邵清鹏
郑欣
曾冬梅
徐国海
SUN Guanghui;SHAO Qingpeng;ZHENG Xin;ZENG Dongmei;XU Guohai(School of Chemistry&Chemical Engineering,Gannan Normal University,Ganzhou 341000,China;Key Laboratory of Jiangxi University for Functional Material Chemistry,Gannan Normal University,Ganzhou 341000,China)
出处
《赣南师范大学学报》
2019年第6期66-69,共4页
Journal of Gannan Normal University
基金
国家自然科学基金资助项目﹙21761003﹚
江西省自然科学基金项﹙2010GQH0022﹚
教育厅科技基金项目(GJJ10716)。
