摘要
以KH550、CH3CH2OH、AgNO3和H2O为原料,制备活化液,实现同时改性和活化PA12粉体,结合化学镀铜工艺,基于"两步法"工艺制备Cu/PA12复合粉体,借助扫描电镜、红外、X射线衍射等分析手段研究PA12粉体表面活化和化学镀机理.结果表明:KH550分子中氨基可吸附Ag+形成直线结构;PA12粉体经活化后形成吸附银颗粒的硅烷包裹在颗粒表面的结构;活化的PA12粉体表面结构可以催化化学镀沉积面心立方铜颗粒,即制备Cu/PA12复合粉体,且随化学镀时间的增加,镀层结晶性能变好,镀层致密度提高.
In this paper,the activation solution was prepared by using ma-aminopropyltriethoxylsilane,CH3CH2OH,H2O and AgNO3 as raw materials,simultaneously modified and activated PA12 powder,combined with electroless copper plating process,Cu/PA12 composite powder was prepared based on the"two-step method".The mechanism of surface activation and electroless plating of PA12 powder was studied by means of SEM,FTIR and XRD.The results showed that the amino group could adsorb Ag+in the KH550 molecule and then formed a linear structure,and the silane adsorbed on silver particles by activated PA12 powder was wrapped on the its surface.The structure of activated PA12 surface can catalyze electroless plating to deposit face-centered cubic copper particles,that is,Cu/PA12 composite powder can be prepared.As the same time,with the increase of electroless plating time,the crystalline property of the coating became better and the density of the coating increased.
作者
蒋超杰
潘万华
陈珍明
桂成梅
韦师
黄俊俊
JIANG Chao-jie;PAN Wan-hua;CHEN Zhen-ming;GUI Cheng-mei;WEI Shi;HUANG Jun-jun(Hefei Jieshijie New Materials Co.Ltd.,Hefei 230009,China;Guangxi Key Laboratory for Comprehensive Utilization of Calcium Carbonate Resources,School of Materials and Chemical Engineering,Hezhou University,Hezhou 542800,China;School of Chemistry and Chemical Engineering,Hefei University of Technology,Hefei 230009,China;School of Energy Materials and Chemical Engineering,Hefei University,Hefei 230601,China)
出处
《安徽化工》
CAS
2020年第2期46-49,52,共5页
Anhui Chemical Industry
关键词
PA12
活化液
化学镀铜
简单工艺
PA12
activation solution
electroless copper plating
facile method
