摘要
众所周知,普通自由基聚合制备的含氟聚合物具有分子量、分子量分布和聚合物结构不易控制等缺点;可逆加成-断裂链转移聚合(RAFT)可以有效克服以上缺点,成为含氟(甲基)丙烯酸酯类聚合物设计与合成的重要工具。综述了近年来含氟(甲基)丙烯酸酯类单体RAFT聚合研究及其应用研究进展,指出可见光诱导的含氟(甲基)丙烯酸酯类单体的RAFT聚合以及聚合诱导的自组装是今后的发展方向。
As we all know,fluoropolymer prepared by traditional free radical polymerization has some disadvantages,such as wide molecular weight distribution and poor control of molecular weight and polymer structure.RAFT polymerization has the merits of controlled free radical polymerization without the shortcoming mentioned above and it can become an important tool for the design and synthesis of fluorinated(meth)acrylate polymers.The recent progress in RAFT polymerization of fluorinated(meth)acrylates and its application were reviewed.It was pointed out that visible light induced RAFT polymerization and polymerization induced self-assembly of fluorinated(meth)acrylates would be the future development directions.
作者
程德书
罗菊香
CHENG De-shu;LUO Ju-xiang(School of Resource and Chemical Engineering,Sanming University,Fujian Sanming 365004,China)
出处
《广州化工》
CAS
2020年第6期20-23,26,共5页
GuangZhou Chemical Industry
基金
2018年度福建省高等学校新世纪优秀人才支持计划(闽教科[2018]47号)
三明市引导性科技项目(2019-G-2)。
