摘要
Classic methods for the synthesis of allenes usually introduce only one functional group into products.In this review,we highlight the recent advances and perspectives in the synthesis of allenes by transition metal-catalyzed 1,4-functionalization of unactivated 1,3-enynes.
基金
financial support from the National Basic Research Program of China(No.973-2015CB856600)
the National NaturalScience Foundation of China(Nos.21532009,21761142010,21790330and 21821002)
the Science and Tech-nology Commission of Shanghai Municipality(Nos.17XD1404500,17QA1405200 and 17JC1401200)
the Strategic Priority Re-search Program(No.XDB20000000)
the Key Research Pro-gram of Frontier Science(QYZDJSSWSLH055)of the Chinese Academy of Sciences.