摘要
N-错位卟啉既是卟啉的同分异构体又是异卟啉的典型代表,也是一类非常重要的卟啉类化合物.因其独特的化学结构及反应活性,近年来引起化学工作者的广泛关注.介绍了N-错位卟啉研究的意义、N-错位卟啉的结构和性质.重点综述了N-错位卟啉的合成及其在催化化学、生物化学和材料化学领域的应用进展.同时对N-错位扩展卟啉和其它错位异卟啉的发展现状作了简要概述,并对N-错位卟啉化学的发展进行了展望.
N-Confused porphyrin, as the typical representative of porphyrinoids, is an isomer of porphyrin. It is an important member of porphyrins, which has attracted extensive attention of chemists recently because of its unique chemical structure and reactivity. Significance, structures and properties of N-confused porphyrins are briefly introduced. Progress in the synthesis of N-confused porphyrins and their applications in the area of catalytic chemistry, biological chemistry and materials chemistry are reviewed emphatically. The development status of expanded N-confused porphyrins and other confused porphyrinoids are also briefly introduced. Further development of N-confused porphyrin chemisty is proposed in the end.
作者
彭素红
周蓉
邹怀波
Peng Suhong;Zhou Rong;Zou Huaibo({College of Chemistry and Bio-engineering,Yichun University,Yichun,Jiangxi 336000)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2019年第12期3384-3398,共15页
Chinese Journal of Organic Chemistry
基金
宜春学院2018地方发展研究中心项目(No.DF2018021)
江西省教育厅科学技术研究项目(No.GJJ180861)
宜春学院博士科研启动基金(No.113-3350100050)资助项目~~
关键词
异卟啉
N-错位卟啉
合成
应用
研究进展
扩展卟啉
porphyrinoids
N-confused porphyrin
synthesis
application
research progress
expanded porphyrin
