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Cu2+在高岭土土柱中运移时的吸附特性研究 被引量:1

Adsorption Characteristics of Cu2+ in Kaolin Column by Sequential Competitive Migration
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摘要 通过土柱实验对比,研究了Cu^2+在高岭土中单一离子运移、两种离子同时运移、两种离子顺序运移时Cu^2+的吸附特性,并与Batch试验的结果进行对比分析,结果表明,在初始浓度、pH相同的条件下,各土柱深度土样对Cu^2+的吸附量均比Batch试验小;运移试验中Cu^2+的单层饱和吸附量Q会随着土层深度的增大而逐渐减小;竞争运移会使高岭土对Cu^2+的吸附量减少;先用Pb2+后用Cu^2+进行顺序运移时,Cu^2+的吸附量显著减少,顺序运移<同时运移<单一离子运移.综合分析不同情况下运移时的Cu^2+在高岭土中吸附特性. The adsorption characteristics of Cu^2+in the kaolin in the single ion transport,the simultaneous transport of two ions,and the sequential transport of the two ions were studied by soil column experiments.The results of the Cu^2+adsorption were compared with the results of the Batch test.The results show that:Under the conditions of the same initial concentration and the same pH,the adsorption amount of Cu^2+in the soil samples of each soil column is smaller than that of the Batch test.The single-layer saturated adsorption amount Q of Cu^2+in the migration test will gradually decrease with the increase of soil depth.The competitive migration will reduce the adsorption of Cu^2+by kaolin.When using Pb2+first and then using Cu^2+for sequential migration,the adsorption amount of Cu^2+is significantly reduced,and the sequential migration<simultaneous migration<single ion migration;The adsorption characteristics of Cu^2+in kaolin during migration under different conditions is comprehensively analyzed.
作者 徐阳阳 艾英钵 范志浩 沙学军 XU Yangyang;AI Yingbo;FAN Zhihao;SHA Xuejun(Geotechnical Engineering Department,Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering,Hohai University,Nanjing 210098,China)
出处 《河南科学》 2019年第11期1790-1795,共6页 Henan Science
基金 中央高校基本科研业务费专项资金(2015B17714)
关键词 CU^2+ Batch试验 土柱实验 顺序竞争 吸附特性 Cu^2+ Batch test soil column experiment sequential competition adsorption characteristics
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