摘要
The modification of graphitic carbon nitride can significantly improve the photocatalytic performance of graphitic carbon nitride(g-C3N4).Fe2O3/nitrogen-deficient g-C3N4-x composite catalysts were prepared with dicyandiamide as the precursor and Fe3+doped in this study.The composite catalysts were characterized by XRD,SEM,FT-IR,XPS and photocurrent measurements.Close interaction occurred between Fe2O3 and nitrogen deficient g-C3N4-x,more photogenerated electrons were created and effectively separated from the holes,resulting in a decrease of photocarrier recombination,and thus enhancing the photocurrent.Photocatalytic performance experiments showed that Fe2O3/nitrogen deficient g-C3N4-x could utilize lowenergy visible light more efficiently than pure g-C3N4,and the removal rate was 92%in 60 minutes.
The modification of graphitic carbon nitride can significantly improve the photocatalytic performance of graphitic carbon nitride（g-C3N4）. Fe2O3/nitrogen-deficient g-C3N4-x composite catalysts were prepared with dicyandiamide as the precursor and Fe3+ doped in this study. The composite catalysts were characterized by XRD, SEM, FT-IR, XPS and photocurrent measurements. Close interaction occurred between Fe2O3 and nitrogen deficient g-C3N4-x, more photogenerated electrons were created and effectively separated from the holes, resulting in a decrease of photocarrier recombination, and thus enhancing the photocurrent. Photocatalytic performance experiments showed that Fe2O3/nitrogen deficient g-C3N4-x could utilize lowenergy visible light more efficiently than pure g-C3N4, and the removal rate was 92% in 60 minutes.
作者
LIU Qi
ZHANG Yi
XIA Shibin
刘琪;ZHANG Shici;LI Ermao;张义;夏世斌(School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,China;State Key Laboratory of Freshwater Ecology and Biotechnology,Institute of Hydrobiology,Chinese Academy of Sciences,Wuhan 430072,China)
基金
Supported by the Fuling Shale Gas Environmental Exploration Technology of National Science and Technology Special Project(No.2016ZX05060)
the Demonstration of Integrated Management of Rocky Desertification and Enhancement of Ecological Service Function in Karst Peak-cluster Depression(No.2016YFC0502400)
National Natural Science Foundation of China(No.51709254)
