摘要
利用傅里叶变换红外光谱仪(FT-IR)、扫描电子显微镜(SEM)和X射线衍射仪(XRD)研究了炭化程度对核桃壳焦孔隙及微晶结构的影响,并使用热重-差示扫描量热仪(TG-DSC)对核桃壳焦及其原料的燃烧特性进行了分析。结果表明,合适的炭化程度(焦炭挥发分含量为6%-15%)使焦炭内乱层石墨变得无序,碳质微晶结构中缺陷增多,导致焦炭内孔隙结构相对发达;热解温度为500℃时,核桃壳焦的比表面积最大,为374.60m2/g;热解温度为600℃时,核桃壳焦的燃烧特性最优,其燃烧特性指数为7.16×106;合适的炭化程度可使焦炭内的挥发分含量减少,从而使得核桃壳焦的高位热值升高,且由于相对发达的孔隙使焦炭在燃烧时与空气的接触面积增大,导致焦炭的燃烧速率加快。
The effect of carbonization degree on pore structure and microstructure of walnut shell chars was studied by Fourier transform infrared spectroscopy (FT-IR),scanning electron microscopy (SEM) and X-ray diffraction (XRD).The combustion characteristics of raw material and walnut shell chars were analyzed using a thermogravimetry coupled with differential scanning calorimeter (TG-DSC).The results show that the appropriate degree of carbonization (volatile content is 6%-15%) leads to the disorderly crystallization of turbostratic and the increase of defects in the carbonaceous microcrystalline structure,which causes a relatively flourishing pore structure and an increase of specific surface.Pyrolysis char at temperature of 500 ℃ has the maximum specific surface area of 374.60 m2/g,while walnut shell char prepared at 600 ℃ has the optimal combustion characteristics with the combustion characteristics index of 7.16×10 6,which indicate that the appropriate carbonization degree of char could reduce the volatile content and increase the higher calorific value of char during combustion process.Moreover,the developed pore structure can increase the contact area between char and air,leading to the accelerated combustion rate of char.
作者
刁瑞
王储
朱谢飞
朱锡锋
DIAO Rui;WANG Chu;ZHU Xie-fei;ZHU Xi-feng(School of Engineering Science,University of Science and Technology of China,Hefei 230026,China)
出处
《燃料化学学报》
EI
CAS
CSCD
北大核心
2019年第10期1173-1180,共8页
Journal of Fuel Chemistry and Technology
基金
国家重点研发计划(2018YFB1501404)资助~~
关键词
炭化程度
微晶结构
比表面积
燃烧特性
高位热值
carbonization degree
microcrystalline structure
specific surface area
combustion characteristic
highercalorific value
