摘要
Low-cost porous calcined dolomite microspheres were prepared by simple spray drying and subsequent calcination. Effects of calcination temperature on phase evolution and adsorption properties of MB were investigated systematically. Results showed that microspheres treated at 400 ℃ kept mainly calcium carbonate (CaMg (CO3)) phase with some small pores, showing better removal efficiency for MB. With the dosage of 20 g/L under the starting concentration of 100 mg/L, the removal efficiency of the microspheres reached 95.6%. The adsorption kinetics data followed the pseudo-second-order kinetic model, and the isotherm data fit the Langmuir isotherm model. The low-cost microsphere could be applied as a promising absorbent for dyes in wastewater filtration and adsorption treatment.
Low-cost porous calcined dolomite microspheres were prepared by simple spray drying and subsequent calcination. Effects of calcination temperature on phase evolution and adsorption properties of MB were investigated systematically. Results showed that microspheres treated at 400 ℃ kept mainly calcium carbonate(CaMg(CO3)) phase with some small pores, showing better removal efficiency for MB. With the dosage of 20 g/L under the starting concentration of 100 mg/L, the removal efficiency of the microspheres reached 95.6%. The adsorption kinetics data followed the pseudo-second-order kinetic model, and the isotherm data fit the Langmuir isotherm model. The low-cost microsphere could be applied as a promising absorbent for dyes in wastewater filtration and adsorption treatment.
作者
YAN Shu
YANG Jinloiig
闫姝;WANG Qinggang;LIU Jingjing;HUO Wenlong;杨金龙;HUANG Yong(State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;School of Civil Engineering, Hebei University of Engineering, Handan 056038, China)
基金
Funded by National Natural Science Foundation of China(Nos.51702184 and 51572140)
China Postdoctoral Science Foundation(No.2017M610085)