摘要
综述了近几年来铜基非贵金属催化剂在甲醇氧化中的研究进展,主要阐述了直接甲醇燃料电池(DMFCs)电化学理论和甲醇氧化的原理,铜的化合物、铜的硫化物和铜的其他材料等基于铜的纳米材料催化剂在甲醇氧化方面的最新研究,给出在甲醇氧化中的最佳性能数据,开发低铂、非铂催化剂对解决铂的成本非常有意义,最后对非贵金属催化剂的未来发展方向做了一些展望。
The research progress of copper-based non-precious metal catalysts in methanol oxidation in recent years is briefly reviewed.The main principles of direct methanol fuel cells(DMFCs)and the principle of methanol oxidation are briefly described.Recent studies on the oxidation of methanol based on copper-based nanomaterial catalysts such as copper compounds,copper sulfides and other copper materials give the best performance data in methanol oxidation.The development of low-platinum and non-platinum catalysts is very meaningful for solving the cost of platinum.Finally,some prospects for the future development of non-precious metal catalysts have been made.
作者
王海涛
夏晓明
孙亚博
奥德
吕美婵
WANG Hai-tao;XIA Xiao-ming;SUN Ya-bo;AO De;L Mei-chan(School of Environmental and Chemical Engineering,Tianjin Polytechnic University,Tianjin 300160,China)
出处
《应用化工》
CAS
CSCD
北大核心
2019年第2期477-481,共5页
Applied Chemical Industry
基金
天津市科委项目(16ZXHLSF00200)
天津市科委项目(17ZYYFSF00010)
天津市科委项目(17ZXHJSF00040)
关键词
铜
非贵金属
甲醇氧化
燃料电池
copper
non-noble metal
methanol oxidation
fuel cell
