摘要
导电聚合物与纤维素纤维的复合可实现功能互补,相应复合材料具有较大利用潜力。本文概述了近年来导电聚合物-纤维素纤维复合材料研究的一些新进展。导电聚合物-纤维素纤维复合材料的制备方法有:原位液相化学聚合法、气相化学聚合法、喷墨打印法、聚电解质吸附法、层层自组装法、吸附胶团聚合法、电化学聚合法等。不同方法各具特色,亦有交叉性与重叠性。其中,原位液相化学聚合法因制备过程简单、成本较低和环境友好而备受关注,已有的研究进展为复合材料在功能纸和水体净化材料等方面的应用奠定了理论基础。在对新进展进行概述的基础上,提出了今后导电聚合物-纤维素纤维复合材料具有发展潜力的研究方向。
The combination of conductive polymers and cellulose fibers to generate composites can lead to integrated functionalities,which would have great application potential.The preparation methods and new research progress of conductive polymer-cellulose fiber composites in recent years were reviewed in this paper.The preparation methods include in-situ liquid-phase chemical polymerization,gas-phase chemical polymerization,inkjet printing,polyelectrolyte adsorption,layer-by-layer self-assembly,admicellar polymerization,electrochemical polymerization,etc.These methods have distinct features,but overlapping may exist in some cases.The in-situ liquid-phase chemical polymerization method has the advantages of simple process,low cost and environmental friendly and is widely used.It is noted that the research progress of in-situ polymerization has significant implications to develop multifunctional paper-based products and bio-based adsorbents for wastewater treatment.The research directions of conductive polymer-cellulose fiber composites in the future were put forward.
作者
韩善九
周万鹏
金海兰
钱学仁
HAN Sun-gu;ZHOU Wan-peng;JIN Hai-lan;QIAN Xue-ren(Key Laboratory of Bio-based Material Science and Technology of Ministry of Education,Northeast Forestry University,Harbin, Heilongjiang Province,150040;Xuancheng Product Quality Supervision and Inspection Institute,Xuancheng,Anhui Province,242000)
出处
《中国造纸学报》
CAS
CSCD
北大核心
2018年第3期68-75,共8页
Transactions of China Pulp and Paper
基金
国家自然科学基金(31170552)
关键词
纤维素纤维
导电聚合物
复合材料
功能纸
原位液相化学聚合法
cellulose fibers
conductive polymers
composite materials
functional paper
in-situ liquid-phase chemical polymerization