摘要
以对氨基苯腈和亚砷酸钠为原料,通过重氮化反应合成了对氰基苯胂酸,产率56%。X射线单晶衍射分析表明目标产物属于单斜晶系,Pnma空间群,晶胞参数:a=98.765(2)?,b=9.788(2)?,c=9.381(2)?,β=94.618(4)o,V=1588.8(5)?3,Z=8。
4-cyanophenylarsonic acid has been synthesized by a typical diazotization reaction,using 4-aminobenzonitrile and sodium arsenite as starting materials.X-Ray diffraction measurement gave out the crystallographic data of title compound:monoclinic system,space group Pnma,a=98.765(2)?,b=9.788(2)?,c=9.381(2)?,β=94.618(4)o,V=1588.8(5)?3,Z=8.
作者
刘莹莹
吴登赟
杨傲
褚少文
刘铂旭
蔡斌
Liu Yingying;Wu Dengyun;Yang Ao;Chu Shaowen;Liu Boxu;Cai Bin(Zhoukou Normal College Chemical Engineering,he'nan,466001)
出处
《当代化工研究》
2018年第1期158-159,共2页
Modern Chemical Research
关键词
对氰基苯胂酸
单晶结构
对氰基苯胺
重氮化反应
4-cyanophenylarsonic acid
single-crystal structure
4-aminobenzonitrile
diazotization reaction
