摘要
介绍了卟啉配合物、酞菁配合物、N-羟基邻苯二甲酰亚胺(NHPI)等含氮化合物在甲苯催化氧化中的研究应用现状。从反应条件、催化活性、使用性能等方面归纳分析了各类含氮化合物在甲苯氧化催化体系中的优缺点。指出今后可以从开发高效可循环的NHPI复合催化体系和探索粗甲苯氧化催化体系两方面深入开展含氮化合物催化氧化甲苯的研究。
The application status of porphyrin complex,phthalocyanine complex and N-hydroxyphthalimide(NHPI)in the catalytic oxidation of toluene were introduced.The advantages and disadvantages of various nitrogenous compounds in the oxidation system of toluene were analyzed from the aspects of reaction conditions,catalytic activity and performance.It was pointed out that the application of nitrogen compounds in toluene oxidation can be carried out from developing the efficient and recyclable NHPI composite catalytic system and exploring the crude toluene oxidation catalyst system.
作者
徐保明
张弘
唐强
张家晖
李俊
李志鹏
霍鹤宇
陈坤
XU Bao-ming;ZHANG Hong;TANG Qiang;ZHANG Jia-hui;LI Jun;LI Zhi-peng;HUO He-yu;CHEN Kun(Hubei Province Postgraduate Workstation,Hubei University of Technology,Wuhan 430068,China)
出处
《应用化工》
CAS
CSCD
北大核心
2018年第3期580-583,共4页
Applied Chemical Industry
基金
科技部中小企业创业基金(12C26214204453)
湖北省教育厅产学研重大项目(CXY2009A010)
关键词
含氮化合物
甲苯
催化氧化
nitrogen-containing compounds
toluene
catalytic oxidation
