摘要
In this work, a direct green solid-phase reduction method for the fabrication of large yield of ordered phase Fe-Pt alloy nanoparticles was reported, in which inorganic salts were used as metal precursors and H_2-containing atmosphere was used as reducer. Utilizing this method, the composition and chemical ordered phase, such as L1_2-Fe_3 Pt, L1_2-FePt_3, and L1_0-FePt phases can be easily achieved by one step reaction. The synthesized nanoparticles have clean surface because no organic precursors, no organic solutions or organic surfactants/ligands were used. Their magnetic performance and the formation mechanism of Fe-Pt alloy nanoparticles were also investigated. This strategy can be applied to synthesize many other types of alloy nanoparticles with desired composition and necessary crystal structure, which can be used for a variety of practical applications, such as in magnetism and catalyst research fields.
In this work, a direct green solid-phase reduction method for the fabrication of large yield of ordered phase Fe-Pt alloy nanoparticles was reported, in which inorganic salts were used as metal precursors and H_2-containing atmosphere was used as reducer. Utilizing this method, the composition and chemical ordered phase, such as L1_2-Fe_3 Pt, L1_2-FePt_3, and L1_0-FePt phases can be easily achieved by one step reaction. The synthesized nanoparticles have clean surface because no organic precursors, no organic solutions or organic surfactants/ligands were used. Their magnetic performance and the formation mechanism of Fe-Pt alloy nanoparticles were also investigated. This strategy can be applied to synthesize many other types of alloy nanoparticles with desired composition and necessary crystal structure, which can be used for a variety of practical applications, such as in magnetism and catalyst research fields.
基金
financially supported by the National Natural Science Foundation of China (Grant Nos.51772220,51772219,51771095,51422106)
Zhejiang Provincial Natural Science Foundation of China (No.D19E010001)
the National Basic Research Program of China (Grant No.2014CB643702)
