摘要
金属有机骨架材料具有比表面积大、有序多孔结构、骨架和金属离子可调等优点,在气体储存、分离、光催化、化学传感、药物缓释等方面具有重要的用途。金属有机骨架材料Ui O-66是由不同有机配体与金属离子Zr构筑而成,一般为正十二面体次级结构单元,具有化学稳定性好、形貌规整可调、热稳定性高、比表面积大等优点。本文综述了近年来功能化Ui O-66在气体吸附、有机染料吸附、荧光传感、药物缓释、光催化等方面的应用研究进展,并对Ui O-66的应用领域进行展望。
Metal-organic frameworks( MOF) have potential applications in the area of gas storage,catalysis,chemical sensing and drug delivery due to their large surface area,adjustable porosities,tunable pore surface,various structures. Ui O-66 is composed of zirconium( Zr) clusters as secondary building units and BDC( 1,4-benzenedicarboxylicacid) as the linkers. This high degree of network connection is believed to account for its exceptional stability,high BET surface area,hydrothermal stability. For the past few years,Ui O-66 has increasingly been attracting interest because of its potential applications,especially in host-guest chemistry fields such as gas separation/adsorption,fluorescent sensing,catalysis,and even as a cell material.
作者
葛金龙
GE Jin-long(School of Material Science Chemical Engineering,Bengbu University,Bengbu Anhui 233000,Chin)
出处
《长春师范大学学报》
2018年第8期77-82,共6页
Journal of Changchun Normal University
基金
安徽省高校自然科学基金重大研究项目(KJ2018ZDBBXY01)
蚌埠学院重点学科"材料科学与工程"(BBXYZDXK201701)
蚌埠学院"新工科"试点专业建设项目"无机非金属材料工程专业"(2017sdzy03)
安徽省质量工程项目卓越人才教育培养计划(2015zjjh036)