摘要
以罗丹明6G螺环酰肼为荧光探针,在水溶液中可选择性检测谷氨酸和天门冬氨酸。在500nm波长激发下,1min内两种样品溶液即发出550nm绿光,检测限分别可达7×10^(-8)mol/L和1.4×10^(-7)mol/L。此外本文还分析了罗丹明6G螺环酰肼能够选择性和高灵敏度快速荧光检测谷氨酸和天门冬氨酸的机理。
A spirocyclic rhodamine 6 G hydrazide was used as fluorescence probe to detect glutamic acid and aspartic acid in aqueous solution.Both sample solution emitted 550 nm green light in 1 minute(the excitation wavelength is 500 nm).The detection limit can be as low as 7×10-8 mol/L and 1.4×10-7 mol/L respectively.Finally,the mechanism of selective and rapid fluorescence detection for glutamic acid and aspartic acid was analyzed.
作者
谢先格
夏方媛
黄苏琴
彭小伟
傅燕
王筱梅
陶绪堂
XIE Xiange;XIA Fangyuan;HUANG Suqin;PENG Xiaowei;FU Yan;WANG Xiaomei;VhO Xutang(Institute of Chemistry,Biology and Materials Engineering,Suzhou University of Science and Technology,Suzhou 215009,Jiangsu,P.R.China;State Key Laboratory of Crystal Materials,Bhandong University,Ji'nan 250100,Shandong,P.R.China)
出处
《影像科学与光化学》
CAS
CSCD
2018年第4期315-323,共9页
Imaging Science and Photochemistry
关键词
罗丹明6G螺环酰肼
荧光探针
谷氨酸
天门冬氨酸
快速荧光检测
spirocyclic rhodamine 6G hydrazide
fluorescence probe
glutamic acid
aspartic acid
rapid fluores-cence detection