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Expedient chemoselective and catalyst-free synthesis of 3,3-difluorochroman-4-ones from o-hydroxyarylenaminones and Selectfluor

Expedient chemoselective and catalyst-free synthesis of 3,3-difluorochroman-4-ones from o-hydroxyarylenaminones and Selectfluor
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摘要 An expedient and mild strategy for the synthesis of unconventional 2-(dimethylamino)-3,3-difluorochroman-4-one derivatives from o-hydroxyarylenaminones and Selectfluor was developed at room temperature under catalyst-free conditions. This method showed excellent chemoselectivity and great functional groups tolerance. An expedient and mild strategy for the synthesis of unconventional 2-(dimethylamino)-3,3-difluorochroman-4-one derivatives from o-hydroxyarylenaminones and Selectfluor was developed at room temperature under catalyst-free conditions. This method showed excellent chemoselectivity and great functional groups tolerance.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2018年第6期963-966,共4页 中国化学快报(英文版)
基金 Financial support from the Recruitment Program of Global Experts (1000 Talents Plan) the Natural Science Foundation of Fujian Province (No. 2016J01064) Fujian Hundred Talents Plan, Program of Innovative Research Team of Huaqiao University (No. Z14X0047) Subsidized Project for Cultivating Postgraduates’ Innovative Ability in Scientific Research of Huaqiao University (for Z. Kuang) are gratefully acknowledged
关键词 SELECTFLUOR o-Hydroxyarylenaminones CATALYST-FREE Chroman-4-one Fluorination reaction Fluorine-contained compound Selectfluor o-Hydroxyarylenaminones Catalyst-free Chroman-4-one Fluorination reaction Fluorine-contained compound
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