摘要
Nitrogen-doped graphene/carbon nanohorns composite(NGLC) was prepared by one-step co-pyrolysis of graphene oxide, carbon nanohorns(CNHs), urea, and lignosulfonate. CNHs as spacers were inserted into graphene nanosheets. The introduction of CNHs and the loosened nano-structure of NGLC make it achieve a high specific capacitance of 363 Fg^(-1) at a discharge current density of 1 A g^(-1), and NGLC exhibits an ultrahigh stability of 93.5% capacitance retention ratio after 5000 cycles. The outstanding comprehensive electrochemical performance of NGLC could meet the need of the future acted as an efficient supercapacitor electrode material.
Nitrogen-doped graphene/carbon nanohorns composite(NGLC) was prepared by one-step co-pyrolysis of graphene oxide, carbon nanohorns(CNHs), urea, and lignosulfonate. CNHs as spacers were inserted into graphene nanosheets. The introduction of CNHs and the loosened nano-structure of NGLC make it achieve a high specific capacitance of 363 Fg^(-1) at a discharge current density of 1 A g^(-1), and NGLC exhibits an ultrahigh stability of 93.5% capacitance retention ratio after 5000 cycles. The outstanding comprehensive electrochemical performance of NGLC could meet the need of the future acted as an efficient supercapacitor electrode material.
基金
support from the National Natural Science Foundation of China (Grant No. 51503041)
the Natural Science Foundation of Fujian Province, China (Grant No. 2016J01729)
the Key Program of Youth Natural Science Foundation of Fujian Province University, China (Grant No. JZ160413)