摘要
以2-氨基-8-羟基喹啉和二茂铁甲醛为原料,设计并合成了一种新型的二茂铁席夫碱化合物,并利用紫外-可见光谱、元素分析、核磁等方法对该化合物的结构进行表征.电化学研究结果表明:该化合物的Epa,Epc,E1/2和ipc/ipa分别为0.304V,0.186V,0.245V,0.97.其氧化还原是可逆的.
A Novel ferrocenoyl schiff-base compound was designed and synthesized from 2-amino-8-hydroxyquinoline and formyl-ferrocen. The structure was fully characterized by elemental analyses,1 H NMR and UV-vis. The electrochemical properties were investigated by voltammogram. The results showed that Epa,Epc,E1/2 and ipc/ipa were 0. 304 V,0. 186 V,0. 245 V,and 0. 97 respectively. The redox process of the compound was reversible.
出处
《南京晓庄学院学报》
2017年第6期5-6,51,共3页
Journal of Nanjing Xiaozhuang University
基金
南京晓庄学院校级科研项目(2015NXY75)
关键词
合成
二茂铁
席夫碱
电化学
synthesis
ferrocene
Schiff-base
electrochemical
