期刊文献+

甲醇制备丙烯装置催化剂再生工艺研究

Study on catalyst regeneration process of methanol to propylene plant
下载PDF
导出
摘要 针对甲醇制丙烯装置催化剂碱金属中毒,烧焦再生处理其活性仍不可完全恢复的问题,在常规再生方法基础上增加离子交换工艺,使催化剂活性得到恢复,甲醇转化率达到99.09%,丙烯选择性达到43.62%。加速老化评价结果表明,在甲醇空速为4.0 h^(-1)条件下,经过34 h后甲醇转化率仍未下降,催化剂寿命显著延长。 The activity of MTP catalyst can not be fully recovered in view of the alkali metal poisoning. On the basis of conventional regeneration method, the ion exchange process was added to recover the activity of the catalyst. The conversion of methanol reached 99.09 % and the selectivity of propylene reached 43.62 %. The results of accelerated aging evaluation showed that the methanol conversion was not decreased and the catalyst life was prolonged significantly after 34 h at the methanol space velocity of 4.0 h^(-1).
作者 蔡力宏 张伟
出处 《石油化工应用》 CAS 2017年第12期110-113,共4页 Petrochemical Industry Application
关键词 甲醇制丙烯 催化剂 烧焦再生 离子交换 转化率 methanol to propylene catalyst coke regeneration ion exchange conversion
  • 相关文献

参考文献2

二级参考文献23

  • 1钟莉,王亚明.分子筛催化剂的再生[J].工业催化,2005,13(2):7-11. 被引量:10
  • 2李燕秋,白尔铮,段启伟.芳烃生产技术的新进展[J].石油化工,2005,34(4):309-315. 被引量:45
  • 3刘俊涛,林衍华,刘国强,徐蟾芬,顾瑞芳,周斌,方永成.异丙苯合成分子筛催化剂的水蒸汽再生[J].工业催化,2005,13(9):24-27. 被引量:1
  • 4靳力文,李春义,余长春,等.SAPO-34分子筛上MTO和烧焦反应的研究[J].石油与天然气化工,2001,30(1):2-6. 被引量:3
  • 5Le M C, Jones R A, Craven I E,et al. Temperature programmed oxi- dation of coke deposited on cracking catalysts : Combustion mecha- nism dependence [ J ]. Energy & Fuels, 1997,11 ( 2 ) :463 - 469. 被引量:1
  • 6Dart J C, Savage R T, Kirkbride C G. Regeneration characteristics of clay cracking catalyst[ J]. Chem Eng Prog, 1949,45 (2) :102 - 110. 被引量:1
  • 7Aguayo A T, Gayubo A G, Atutxa A, et al. Regeneration of a cata- lyst based on a SAPO-34 used in the transformation of methanol in- to olefins[ J], Journal of Chemical Technology and Biotechnology, 1999,74 ( 11 ) :1082 - 1088. 被引量:1
  • 8Dahl I M, Kolboe S. On the reaction-mechanism for hydrocarbon formation in the MTO reaction over SAPO-34 [ J ]. Catal Lett, 1993, 20(3/4) :329 -336. 被引量:1
  • 9Lee Y J, Beak S C, Jun K W. Methanol conversion on SAPO-34 cat- alysts prepared by mixed template method[ J], Appl Catal A:Gen, 2007,329 ( 1 ) : 130 - 136. 被引量:1
  • 10Bilbao J, Arandes J M, Romero A ,et al. Kinetic study of the regen- eration of solid catalysts under internal diffusion restriction [ J ]. Chem Eng J,1987,35(2) :115 - 122. 被引量:1

共引文献17

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部