摘要
在常规反应器中利用原位插层法的原理,制备了聚苯撑苯并二噁唑/纳米石墨微片(PBO/GN)复合材料。该反应在常规反应器中能顺利进行,避免使用双螺杆挤出机等高端设备,大大降低了反应成本。对PBO/GN复合材料进行了红外及热重分析、特性黏数比较和力学性能测定,与同等条件下制得的PBO进行了对比分析。结果表明:GN对PBO的聚合有促进作用,制得的PBO/GN复合材料不仅具有PBO材料优良的耐热性,纤维拉伸强度也相对提高了90%左右。
In the conventional reactor by in situ in the principle of layer,the poly-phenylene benzobisoxazole/graphite nanosheet（PBO/GN）composite materials were prepared.The reaction can be carried out smoothly in the conventional reactor,so as to avoid used double screw extruder and other high-end equipment,greatly reducing the reaction cost.The infrared analysis,thermogravimetric analysis,characteristic viscosity and mechanical properties of PBO/GN were analyzed,and the PBO was compared under the same conditions.The experimental results showed that the graphite nanosheet（GN）had a promoting effect on the polymerization of PBO.The prepared PBO/GN not only had excellent heat resistance and mechanical properties of PBO composites,but also improved the mechanical properties of composites.
作者
张鹏程
许红红
蒋文伟
杨琴
罗芹
Zhang Pengcheng Xu Honghong Jiang Wenwei Yang Qin Luo Qin(School of Chemical Engineering, SCU, Chengdu 610065 Chengdu Hui,en Fine Chemical Co. ,Ltd.,Chengdu 610065)
出处
《化工新型材料》
CAS
CSCD
北大核心
2017年第10期80-81,84,共3页
New Chemical Materials
