摘要
Oxone?因其绿色、廉价、安全等特点被广泛应用于各类氧化反应中.本文以Oxone?为氧化剂,n-Bu4NBr为催化剂,室温下紫外照射1h,将醇氧化为相应的羰基化合物,并对反应机理进行了讨论.该催化体系的底物适用范围广,可将芳香醇及其衍生物高效地氧化为醛酮化合物,且对产物有较好的选择性,反应体系温和、无毒,是一种高效的绿色催化氧化方法.
Oxone？is widely applied in the field of oxidation reaction for it is green,cheap,safe and commercially available.This paper presents a method of photo-oxidation of alcohols using Oxone？catalyzed by n-Bu4 NBr at room temperature in water under irradiation of UV for 1h.Besides,the plausible mechanism for the oxidation of alcohols is discussed.The substrate of the catalytic system has a wide range of application and its derivatives will be oxidized to carbonyl compounds.Moreover,for its good selectivity of the products,mild reaction system and non-toxic,it is an efficient green catalytic oxidation method.
作者
杨全录
许守旺
吴尚
YANG Quan-lu XU Shou-wang WU Shang(College of Chemical Engineering, Lanzhou University of Arts and Science, Lanzhou 730000, Chin)
出处
《兰州文理学院学报（自然科学版）》
2017年第5期41-45,共5页
Journal of Lanzhou University of Arts and Science(Natural Sciences)
