摘要
以CO_2与环氧化物合成环状碳酸酯为研究对象,综述了有机碱催化剂、碱金属卤化物催化剂、酸碱性催化剂、金属配合物催化剂、杂多酸盐催化剂、离子液体催化剂6类均相催化剂的研究进展,并就其催化活性进行了比较,探讨了未来均相催化剂的发展前景。
Taking the synthesis of cyclic carbonates from carbon dioxide and epoxides as study object,this paper reviews the research progress on six kinds of homogeneous catalysts including organic base catalysts,alkali metal halides catalysts,acid and base catalysts,metal complex catalysts,polyoxometalates catalysts and ionic liquid catalysts. The comparison between them has been carried out. In addition,the prospect for homogeneous catalysts in the future is discussed.
作者
赵黎业
黄雪莉
ZHAO Li-ye HUANG Xue-li(College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, Chin)
出处
《现代化工》
CAS
CSCD
北大核心
2017年第10期60-64,共5页
Modern Chemical Industry
关键词
环状碳酸酯
均相催化剂
CO2
环氧化物
cyclic carbonates
homogeneous catalysts
carbon dioxide
epoxide
