摘要
以低温燃烧合成法制备了Ba_xNa_yY_zF_(2x+y+3z+3 m):Er_m^(3+)上转换荧光粉,通过X射线衍射仪和扫描式电子显微镜对荧光粉的物相及形貌进行分析,采用正交实验法得出最佳配方。通过测试Er^(3+)和Y^(3+)掺杂浓度不同的样品的上转换发光性能,研究了掺杂浓度对红绿光上转换的影响。结果表明:增大Y^(3+)的掺杂浓度,有利于绿光上转换过程;增大Er^(3+)的掺杂浓度,有利于红光上转换过程。
Up-conversion phosphor BaxNayYzF2x+y+3z+3m :Er^3+ mis synthesized by low-temperature combustion synthesis method.The phase and morphology of the phosphor are analyzed by X-ray diffraction and scanning electron microscopy,and the optimal formula is obtained by orthogonal experiment.The effects of doping concentration of Er^3+ and Y^3+ ions on green and red up-conversion is studied by measuring the up-conversion luminescence property of samples with different doping concentrations.The results show that increasing the doping concentration of Y3+ion is beneficial to green up-conversion luminescence,increasing the doping concentration of Er^3+ ion is beneficial to red up-conversion luminescence.
作者
巩小萌
邹业国
赵秋爽
米晓云
卢利平
Gong Xiaomeng Zou Yeguo Zhao Qiushuang Mi Xiaoyun Lu Liping(College of Materials Science and Engineering, Changchun University of Science and Technology Changchun, Jilin 130022, China)
出处
《中国激光》
EI
CAS
CSCD
北大核心
2017年第10期98-104,共7页
Chinese Journal of Lasers
基金
国家自然科学基金(61307118
51602027)
吉林省教育厅项目(JJKH20170607KJ)
关键词
材料
上转换发光
发光强度比
Er3+发光
materials
up-conversion luminescence
luminescence intensity ratio
Er^3+ luminescence