摘要
The enhanced composite nanofibers have attracted great attention for application in recent years. The electrospinning technique was considered to be a prospective production pattern for them. This paper provided a promising technique to prepare the polyacrylonitrile （PAN）/halloysite nanotube （HNT） composite nanofbers by using the electrospinning method. The PAN/HNTs composite nanofbers with well enhanced performance were successfully fabricated from a mixture of PAN/DMF/HNTs dispersion solution processed by the electrospinning technique. For achieving good dispersion in PAN polymer, the highly dispersed HNTs were obtained by using polycarboxylate modifcation employing the in-situ spray-drying method. The structure and properties of the composite nanofbers were characterized by TEM, XRD, EDX, IR, and DSC techniques. The obtained PAN/HNTs composite nanofbers with different HNTs contents were about 300-500 nm in diameter. In addition, the mechanical properties of PAN/HNTs composite nanofbers were tested, which exhibited an excellently enhanced performance.
The enhanced composite nanofibers have attracted great attention for application in recent years. The electrospinning technique was considered to be a prospective production pattern for them. This paper provided a promising technique to prepare the polyacrylonitrile(PAN)/halloysite nanotube(HNT) composite nanofibers by using the electrospinning method. The PAN/HNTs composite nanofibers with well enhanced performance were successfully fabricated from a mixture of PAN/DMF/HNTs dispersion solution processed by the electrospinning technique. For achieving good dispersion in PAN polymer, the highly dispersed HNTs were obtained by using polycarboxylate modification employing the in-situ spray-drying method. The structure and properties of the composite nanofibers were characterized by TEM, XRD, EDX, IR, and DSC techniques. The obtained PAN/HNTs composite nanofibers with different HNTs contents were about 300—500nm in diameter. In addition, the mechanical properties of PAN/HNTs composite nanofibers were tested, which exhibited an excellently enhanced performance.
基金
supported by the Talent Introduction Fund of Yangzhou University (2012)
the Key Research Project-Industry Foresight and General Key Technology of Yangzhou (YZ2015020)
the Innovative Talent Program of Green Young Golden Phoenix (yzlyjfjh2015CX073)
the Yangzhou Social Development Project (YZ2016072)
the Six Talent Peaks of Jiangsu province (2014-XCL-013)
the Jiangsu Province Science and Technology Support Project (BE2014613)
the Jiangsu Industrial-Academic-Research Prospective Joint Project ( BY2016069-02)
