摘要
以2,2’-联吡啶(BIPY)和苯甲酸钠为共原料,和氯化钴反应合成了一种新型的钴配合物[Co(BIPY)(C_6H_5COO)_2],并通过扩散法得到了该配合物的单晶。通过X-射线单晶衍射、元素分析、红外光谱对该配合物进行了结构表征。晶体结构表明:该分子结构中,钴配位中心分别与一个2,2’-联吡啶和两个苯甲酸配位。我们还对该配合物的热稳定性进行了研究。
With 2,2＇-Bipyridyl （BIPY is 2,2＇-BipyridyI） and sodium benzoate as raw materials, a novel cobalt complex with the formul of [Co（BIPY）（C6H5COO）2] was synthesized and the single crystal was obtained by diffusion method. The complex was characterized by elemental analysis, IR, and single crystal X-ray diffraction analysis. Single crystal structure shows that the cobalt center was coordinated with 2,2＇-Bipyridyl and two benzoic acid ligand. We also studied the thermal stability of the complexes.
出处
《广东化工》
CAS
2017年第6期70-71,共2页
Guangdong Chemical Industry
