摘要
Li-ion hybrid capacitors（LIHCs）,composing of a lithium-ion battery（LIB） type anode and a supercapacitor（SC） type cathode,gained worldwide popularity due to harmonious integrating the virtues of high energy density of LIBs with high power density of SCs.Herein,nanoflakes composed microflower-like Co-Ni oxide（CoNiO） was successfully synthesized by a simple co-precipitation method.The atomic ratio of as-synthesized CoNiO is determined to be 1：3 through XRD and XPS analytical method.As a typical battery-type material,CoNiO and capacitor-type activated polyanilinederived carbon（APDC） were used to assemble LIHCs as the anode and cathode materials,respectively.As a result,when an optimized mass ratio of CoNiO and APDC was 1：2,CoNiO//APDC LIHC could deliver a maximum energy density of 143 Wh kg^-1 at a working voltage of 1-4 V.It is worth mentioning that the LIHC also exhibits excellent cycle stability with the capacitance retention of -78.2%after 15,000 cycles at a current density of 0.5 A g^-1.
Li-ion hybrid capacitors（LIHCs）,composing of a lithium-ion battery（LIB） type anode and a supercapacitor（SC） type cathode,gained worldwide popularity due to harmonious integrating the virtues of high energy density of LIBs with high power density of SCs.Herein,nanoflakes composed microflower-like Co-Ni oxide（CoNiO） was successfully synthesized by a simple co-precipitation method.The atomic ratio of as-synthesized CoNiO is determined to be 1：3 through XRD and XPS analytical method.As a typical battery-type material,CoNiO and capacitor-type activated polyanilinederived carbon（APDC） were used to assemble LIHCs as the anode and cathode materials,respectively.As a result,when an optimized mass ratio of CoNiO and APDC was 1：2,CoNiO//APDC LIHC could deliver a maximum energy density of 143 Wh kg^-1 at a working voltage of 1-4 V.It is worth mentioning that the LIHC also exhibits excellent cycle stability with the capacitance retention of -78.2%after 15,000 cycles at a current density of 0.5 A g^-1.
基金
supported by the National Nature Science Foundations of China(Nos.21573265 and 51501208)
