摘要
以2,2’-二吡啶胺(Hdpa)和邻甲基苯甲酸(o-Hmba)为原料,分别和氯化镍、氯化钴反应生成了两种新型的镍、钴配合物[M(Hdpa)2(o-mba)]Cl(M=Ni、Co),并通过扩散法得到了配合物的晶体。通过X-射线单晶衍射、元素分析对配合物进行了结构表征。晶体结构表明:这两种配合物为同构的阳离子-阴离子型化合物。我们还对这两种配合物的质谱(ESI)进行了研究。
With 2,2 ＂- dipyridylamine, o - methylbenzoic acid and nickel chloride or cobalt chloride respectively as rawmaterials, two novel complexes with the formula of [ M （I-Idpa） 2 （ o - mba） ] CI （ where M = Ni or Co metal ion, Hdpa is 2,2＇ -dipyridylamine, o - mba is o - methylbenzoate anion） were synthesized and the single crystals were obtained by diffusion method.The complexes were characterized by elemental analysis and single crystal X - ray diffraction analysis. Single crystal structuresshow that the geometries of the two complexes are isostructural and they are caion - anion species. We also studied the massspectra （ESI） of the complexes.
作者
邓元
李丽
Deng Yuan Li Li(Jining Environmental Protection Monitoring Station, Jining 272100, China High -tech Industrial Department Zone Branch of Jining Environmental Protection Bureau, Jining 272100,China)
出处
《山东化工》
CAS
2017年第5期22-23,26,共3页
Shandong Chemical Industry
关键词
配合物
晶体结构
阴阳离子配合物
complex
crystal structure
cation - anionic complex
